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Slosson, Edwin E., 1865-1929

"Creative Chemistry Descriptive of Recent Achievements in the Chemical Industries"


So when acetylene gas mixed with other gases is passed over a catalyst,
such as a heated mass of iron ore or clay (hydrates or silicates of iron
or aluminum), it forms all sorts of curious combinations. In the
presence of steam we may get such simple compounds as acetic acid,
acetone and the like. But when three acetylene molecules join to form a
ring of six carbon atoms we get compounds of the benzene series such as
were described in the chapter on the coal-tar colors. If ammonia is
mixed with acetylene we may get rings with the nitrogen atom in place of
one of the carbons, like the pyridins and quinolins, pungent bases such
as are found in opium and tobacco. Or if hydrogen sulfide is mixed with
the acetylene we may get thiophenes, which have sulfur in the ring. So,
starting with the simple combination of two atoms of carbon with two of
hydrogen, we can get directly by this single process some of the most
complicated compounds of the organic world, as well as many others not
found in nature.
In the development of the electric furnace America played a pioneer
part.


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