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Slosson, Edwin E., 1865-1929

"Creative Chemistry Descriptive of Recent Achievements in the Chemical Industries"

But even
small doses have such an effect upon the heart action for days afterward
that a slight exertion may prove fatal.
The compound manufactured in largest amount in America was chlorpicrin.
This, like the others, is not so unfamiliar as it seems. As may be seen
from its formula, CCl_{3}NO_{2}, it is formed by joining the nitric acid
radical (NO_{2}), found in all explosives, with the main part of
chloroform (HCCl_{3}). This is not quite so poisonous as phosgene, but
it has the advantage that it causes nausea and vomiting. The soldier so
affected is forced to take off his gas mask and then may fall victim to
more toxic gases sent over simultaneously.
Chlorpicrin is a liquid and is commonly loaded in a shell or bomb with
20 per cent. of tin chloride, which produces dense white fumes that go
through gas masks. It is made from picric acid (trinitrophenol), one of
the best known of the high explosives, by treatment with chlorine. The
chlorine is obtained, as it is in the household, from common bleaching
powder, or "chloride of lime.


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